Hydroformylation of 7-TETRADECENE (cas 10374-74-0) using Rh-TPPTS in a microemulsion
-
Add time:07/30/2019 Source:sciencedirect.com
Water soluble rhodium catalyst complexes are highly active in a microemulsion system stabilized by technical grade surfactants of the alkyl-polyglycolether type. At temperatures around 120 °C and pressures of 100 bar internal alkenes are hydroformylated with high regioselectivity. 7-TETRADECENE (cas 10374-74-0) as model alkene was effectively hydroformylated in microemulsions with high reaction rates yielding 2-hexyl-nonal. Under the reaction conditions applied the equilibria between different catalytically active complexes are shifted towards the unmodified HRh(CO)3. Easy catalyst recycling of the water soluble modified complex is possible when the equilibrium is shifted back under work-up conditions.
We also recommend Trading Suppliers and Manufacturers of 7-TETRADECENE (cas 10374-74-0). Pls Click Website Link as below: cas 10374-74-0 suppliers
Prev:Hydroformylation of the post-metathesis product 7-TETRADECENE (cas 10374-74-0) using rhodium(I) Schiff base derived precatalysts
Next:Synthesis and in vitro antitumor activity of novel acylspermidine derivative N-(4-aminobutyl)-N-(3-aminopropyl)-8-hydroxy-dodecanamide (AAHD) against HepG2 cells) - 【Back】【Close 】【Print】【Add to favorite 】