First total synthesis of new diglycosides, neohancoside A (cas 134553-54-1), and B from Cynanchum hancockianum

Add time:07/30/2019    Source:sciencedirect.com

First total synthesis of monoterpene diglycosides, neohancosides A (1) and B (2) from Cynanchum hancockianum were achieved stereoselectively using fluoride as a glycosyl donor. The absolute configurations of 1 and 2 were determined by enzymatic degradation of synthetic intermediates

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