Mononuclear and dinuclear chiral vanadium(V) complexes with tridentate Schiff bases derived from R(−)-1,2-Diaminopropane (cas 10424-38-1): Synthesis, structure, characterization and catalytic properties

Add time:08/05/2019    Source:sciencedirect.com

A series of vanadium(V) complexes with unsymmetrical tridentate Schiff base ligands, obtained by the single condensation of R(−)-1,2-diaminopropane with salicylaldehyde and its derivatives, 2-hydroxy-1-naphthaldehyde, 2-hydroxyacetophenone, 1-hydroxy-2-acetonaphthone and 2-hydroxybenzophenone, were prepared. The complexes were characterized by elemental analysis and by their IR, CD, UV–Vis, 1D (1H, 51V) and 2D (COSY, NOESY, gHSQC) NMR spectra. Crystal structures of the mononuclear complex {R(−)-2-amino-1-N-[(2′-oxido-κO-4′,6′-dimethoxyphenyl)methylene]aminopropane-κ2N}dioxidovanadium(V), VO2(C12H17N2O3), 4, and of the dinuclear complex, di-μ-oxido-bis({R(−)-2-[1-(2-aminopropylimino)ethyl]-4-methylphenolato-κ3N,N′,O}oxidovanadium(V)), V2O4(C11H15N2O)2, 5, have been obtained by X-ray diffraction studies. The structure of 4 was revealed to be a distorted trigonal–bipyramidal coordination geometry, rarely encountered in VO2(tridentate Schiff base) complexes. Complexes 2 and 3 have the ability to catalyze the oxidation of prochiral sulfide substrates PhSR (R = Me, Bz) utilizing hydrogen peroxide or cumene hydroperoxide (CHPO) as the oxidant.

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