New synthesis of (±)-2-piperazinecarboxylic acid.

Add time:07/31/2019    Source:sciencedirect.com

(±)-2-Piperazinecarboxylic acid is prepared from N-carbethoxy-4-piperidone by α Schmidt rearrangement followed by bromation of the lactam; then α Favorskii rearrangement on the monobromolactam intermediate afforded the desired product.

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