Recovery of silver from nickel electrolyte using corn stalk-based sulfur-bearing adsorbent

Add time:08/01/2019    Source:sciencedirect.com

A renewable and recyclable adsorbent was synthesized by introducing thiol (CSH), episulfide (CSC ring) and thion (CS) groups onto the surface of corn stalks with epithiochlorohydrine as a crosslinker (OCS-ET-TU). The adsorption capacity of OCS-ET-TU for [AgCl4]3− reached to 79.94 mg∙g−1 at the acid concentration of 1.0 mol∙L−1 when the concentrations of Cu(II) and Ni(II) all reached to 10,000 mg∙L−1; the maximum selectivity coefficients of the OCS-ET-TU for Ag(I)/Cu(II) and Ag(I)/Ni(II) achieved to 2.95 and 3.37, respectively. The FT-IR and XPS results showed that [AgCl4]3− as soft acid could easily interact with the sulfur-containing groups belonging to the OCS-ET-TU as soft base. The adsorption and regeneration results of corn stalk-based OCS-ET-TU presented that it can potentially apply for recovery of trace amount of silver anions. The investigation provides a new and high-efficient biomaterial to enrich Ag(I) from nickel electrolyte with high concentrations of copper, iron and nickel.

We also recommend Trading Suppliers and Manufacturers of sulphuric acid, silver salt (cas 19287-89-9). Pls Click Website Link as below: cas 19287-89-9 suppliers

Prev:Study of reaction dynamics of photocatalytic degradation of 4-chlorophenol using SrTiO3, sulfur doped SrTiO3, silver metallized SrTiO3 and silver metallized sulfur doped SrTiO3 catalysts: Detailed analysis of kinetic results
Next:Silver nanoparticles for selective detection of phosphorus pesticide containing π-conjugated pyrimidine nitrogen and sulfur moieties through non-covalent interactions)