Indication of bivariance in the phase system SODIUM ZIRCONATE (cas 12201-48-8)/zirconia

Add time:08/01/2019    Source:sciencedirect.com

The sodium oxide activity established by the equilibrium between Na2ZrO3(s) and ZrO2(s) is subject to a continual change upon varying the composition of the phase mixture. This is revealed from the results of a solid state electrochemical approach that allows sensitive differentiation between univariance and bivariance of the phase equilibrium under consideration, thus indicating the occurrence of a noticeable sodium nonstoichiometry presumably in sodium zirconate.

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