Mixed arsonium–iodonium and sulfonium–iodonium ylides: synthesis and characteristics

Add time:08/01/2019    Source:sciencedirect.com

The preparation and properties of novel mixed arsonium–iodonium and sulfonium–iodonium ylides are reported. A series of substituted arsonium and sulfonium ylides was obtained by the nucleophilic substitution of iodonium groups in mixed ylides. A one-pot process, which included the nucleophilic substitution and silylation of arsonium–iodonium ylides with subsequent elimination of the silyl group and a Wittig olefination reaction, provided route to access Z-α,β-unsaturated haloketones.

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