Enzymatic preparation of (3S,6R) and (3R,6S)-3-hydroxy-6-acetoxycyclohex-1-ene

Add time:08/01/2019    Source:sciencedirect.com

Pseudomonas cepacia lipase-catalyzed enantioselective hydrolysis of 2 in water afforded (3S,6R)-3. The antipode (3R,6S)-3 was prepared by enantioselective acylation of 4 using the same enzyme.

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