Synthesis, crystal structure and triboluminescence spectrum of 1,4-DIMETHYLPYRIDINIUM (cas 18241-35-5) tetrakis (2-thenoyltrifluoroacetonato)europate

Add time:08/01/2019    Source:sciencedirect.com

Triboluminescent phenomenon of 1,4-DIMETHYLPYRIDINIUM (cas 18241-35-5) tetrakis(then oyltrifluoroacetonato) europate (1) was firstly observed. Its crystal structure and the triboluminescent spectrum were successfully determined. The crystal is centrosymmetric and the Eu atom exhibits an eight-coordinate tetragonal anti-prismatic geometry. The triboluminescent spectrum of 1 is basically similar to that of photoluminescent spectrum and the observed triboluminescent emission correlates with the disorders of the S atoms and F atoms.

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