Electroreductive nucleophile acceptor generation. Electrochemical synthesis of N-(4-(dimethylamino)phenyl)benzenesulfonamide

Add time:08/03/2019    Source:sciencedirect.com

To the best of our knowledge, this is first report describing generation of Michael acceptor via electrochemical reduction. In this work, electrochemical reduction of 4-nitroso-N,N-dimethylaniline has been studied in the presence of arylsulfinic acids in aqueous solutions. The cathodically generated p-quinonediimine participates in Michael type addition reaction with arylsulfinic acids and converts to the corresponding sulfonamide derivatives. This work has led to the development of a facile and environmentally friendly reagent-less electrochemical method for the synthesis of some sulfonamide derivatives with safe waste under green conditions.

We also recommend Trading Suppliers and Manufacturers of (Z)-3-(dimethylamino)-1-methyl-3-oxoprop-1-enyl dimethyl phosphate (cas 18250-63-0). Pls Click Website Link as below: cas 18250-63-0 suppliers

Prev:Perspective on quantifying electron localization/delocalization, non-linear optical response and vibrational analysis of 4-(dimethylamino)benzaldehyde-2,4-dinitroaniline
Next:Thalictrum alkaloids—IV)