Half-sandwich d6 metal complexes with bis(pyridine carboxamide)benzene ligand: Synthesis and spectral analysis

Add time:08/02/2019    Source:sciencedirect.com

The reactions of [(arene)MCl2]2 dimers with the 1,4-bis(2-pyridine carboxamido)benzene (H2L) have been reported here with the formulations as [(arene)MCl(HL)] {where, arene = p-cymene, M = Ru (1), arene = Cp*, M = Rh (2) and Ir (3)}and [{(arene)MCl}2L] {where, arene = p-cymene, M = Ru (4), arene = Cp*, M = Rh (5) and Ir (6)}, which resulted in a series of mono- and di-nuclear neutral complexes. These complexes have been characterized by various spectral analyses. Complexes 2–6 are additionally described by the single crystal X-ray diffraction studies. Single crystal X-ray analyses of complexes showed that they are neutral in nature and vicinity around the metal is distorted octahedral. The chloride atoms and Cp* moieties are in cis orientation with respect to the ligand in the case of complex 6. Complexes 2, 3 and 5 are crystallized with the solvent dichloromethane molecule.

We also recommend Trading Suppliers and Manufacturers of BENZENE-D6 (cas 1076-43-3). Pls Click Website Link as below: cas 1076-43-3 suppliers

Prev:Preparation of 2-methyl-1,4-naphthoquinone (vitamin K3) by catalytic oxidation of 2-methyl-1-naphthol in the presence of iron phthalocyanine supported catalyst
Next:A crossed molecular beam study on the reaction of boron atoms, B(2Pj), with benzene, C6H6(X1A1g), and D6-benzene C6D6(X1A1g))