The assembly of two isomorphous coordination compounds based on 1,4-Cyclohexanedicarboxylic acid (cas 1076-97-7) and 2,4-diamino-6-phenyl-1,3,5-triazine

Add time:08/02/2019    Source:sciencedirect.com

The compounds [Co(e,a-cis-1,4-chdc)(phdat)]n (1) and [Cd(e,a-cis-1,4-chdc)(phdat)]n (2) have been synthesized under hydrothermal method by using 1,4-Cyclohexanedicarboxylic acid (cas 1076-97-7) (1,4-H2chdc), 2,4-diamino-6-phenyl-1,3,5-triazine (phdat) as well as CoCl2·6H2O, CdCl2·2.5H2O respectively and characterized by IR spectra, X-ray single-crystal diffraction, powder X-ray single-crystal diffraction (PXRD), elemental analyses and thermogravimetric analyses (TGA). The results show the compounds 1 and 2 are isomorphous and exhibit paddle-wheel dinuclear Co2(CO2)4/Cd2(CO2)4 units, which are further connected to 1D chain structures by μ4:η1:η1:η1:η1 1,4-chdc2– ligands and extended into a 3D structures via different hydrogen bonding and π…π stacking interactions. Furthermore, compound 1 exhibits antiferromagnetic behavior and compound 2 displays luminescent behavior at solid state.

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