Reversible structural transformations of rubidium and cesium amidoboranes

Add time:08/05/2019    Source:sciencedirect.com

Rubidium and cesium amidoboranes were obtained using a reaction of the respective alkali metal with ammonia borane in THF solution at 0 °C. Both solid compounds undergo a reversible phase transition before irreversible thermal decomposition with hydrogen evolution, as illustrated by STA, PXRD and NMR measurements.

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