Nitridorhenium(V) and nitridotechnetium(V) complexes with 2-(diphenylphoshinomethyl)aniline
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Add time:07/14/2019 Source:sciencedirect.com
Reactions of 2-(diphenylphosphinomethyl)aniline, H2L1, with [MNCl2(PPh3)2] complexes (M = Re, Tc) give the bis-chelates [MNCl(H2L1)2]Cl (M = Re, Tc) or the mono-chelate [ReNCl2(PPh3)(H2L1)] depending on the conditions applied. The aminophosphine reacts as a bidentate, neutral ligand in all three cases. The complexes were studied spectroscopically and by X-ray crystallography.
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