Hydrolysis of cellulose catalyzed by quaternary ammonium perrhenates in 1-allyl-3-methylimidazolium chloride

Add time:08/05/2019    Source:sciencedirect.com

Quaternary ammonium perrhenates were applied as catalyst to promote the hydrolysis of cellulose in 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The quaternary ammonium perrhenates displayed good catalytic performance for cellulose hydrolysis. Water was also proven to be effective to promote cellulose hydrolysis. Accordingly, 97% of total reduced sugar (TRS) and 42% of glucose yields could be obtained under the condition of using 5 mol% of tetramethyl ammonium perrhenate as catalyst, 70 μL of water, ca. 0.6 mmol of microcrystalline cellulose (MCC) and 2.0 g of [Amim]Cl as solvent under microwave irradiation for 30 min at 150 °C (optimal conditions). The influence of quaternary ammonium cation on the efficiency of cellulose hydrolysis was examined based on different cation structures of perrhenates. The mechanism on perrhenate catalyzed cellulose hydrolysis is also discussed, whereas hydrogen bonding between ReO4 anion and hydroxyl groups of cellulose is assumed to be the key step for depolymerization of cellulose.

We also recommend Trading Suppliers and Manufacturers of TETRABUTYLAMMONIUM PERRHENATE (cas 16385-59-4). Pls Click Website Link as below: cas 16385-59-4 suppliers

Prev:Rearrangement of Allylic and Propargylic Alcohols Catalyzed by the Combined Use of TETRABUTYLAMMONIUM PERRHENATE (cas 16385-59-4) (VII) and p-toluenesulfonic acid
Next:Design, synthesis and biological evaluation of novel pyrrole derivatives as potential ClpP1P2 inhibitor against Mycobacterium tuberculosis)