Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV); single ion hydration enthalpies of the hexafluororhenate(IV) and hexafluororuthenate(IV) anions

Add time:08/04/2019    Source:sciencedirect.com

Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV) in water at 298.2K have been determined by direct calorimetry. They are +63.0 ± 0.3 and +59.4 ± 1.5 kJ mol-1 respectively. From these results single ion hydration enthalpies of −999 and −967 kJ mol-1 have been estimated for the (gaseous) hexafluororhenate(IV) and hexafluororuthenate(IV) anions.

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