Chemical and electrochemical reduction of diselenide dication salt, 1,5-diselenoniabicyclo[3.3.0]Octane bis(hexafluorophosphate)

Add time:08/05/2019    Source:sciencedirect.com

The reaction of the diselenide dication salt, 1,5-diselenoniabicyclo[3.3.0]octane bis(hexafluorophosphate) (1) with 1,5-diselenacyclooctane (2) gave the corresponding cation radical by single-electron transfer. The dication salt 1 was reduced upon treatment with fluorenyl-lithium, Na2S, NaBH4; it did not deprotonate. The cyclic voltammetry of 1 shows the reversible reduction peak at remarkably low reduction potential.

We also recommend Trading Suppliers and Manufacturers of NITROSONIUM HEXAFLUOROPHOSPHATE (cas 16921-91-8). Pls Click Website Link as below: cas 16921-91-8 suppliers

Prev:Reactions of NITROSONIUM HEXAFLUOROPHOSPHATE (cas 16921-91-8) with some olefinic compounds in acetonitrile: one step synthesis of 4H-5,6-dihydro-1,2-oxazines
Next:The enthalpies of formation of iodine pentafluoride and IODINE HEPTAFLUORIDE (cas 16921-96-3))