Selective reduction of 1-chloro-2-iodoperfluorocycloalkenes with SODIUM TRIMETHOXYBOROHYDRIDE (cas 16940-17-3)

Add time:08/04/2019    Source:sciencedirect.com

In contrast to other chemical reducing agents, it has been found that sodium trimethoxyborohydride will selectively reduce 1-chloro-2-iodoperfluorocycloalkenes to give good yields of 1-hydro-2-chloroperfluorocycloalkenes. The selective displacement of iodine by hydrogen is discussed in terms of HSAB principles.

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