Thermal decomposition of caesium permanganate

Add time:08/05/2019    Source:sciencedirect.com

A kinetic study of the thermal decomposition of caesium permanganate confirms previous observations by P.J. Herley and E.G. Prout (J. Chem. Soc. (1959) 3300). Our scanning electron microscope, high magnification examination of the textures of product and of partially decomposed samples provides evidence that reaction is accompanied by melting. Accordingly we here reconsider the reaction mechanism and conclude that anion breakdown proceeds through electron transfer between anions 2MnO−4 → MnO·-4 + [MnO4 → MnO2−4 + MnO2 + O2, within a local intracrystalline molten phase resulting from fusion of a (CsMnO4+Cs2MnO4) eutectic.

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