Nickel-based catalysts for hydrogen evolution by hydrolysis of sodium borohydride: from structured nickel HYDRAZINE NITRATE (cas 13464-97-6) complexes to reduced counterparts

Add time:08/05/2019    Source:sciencedirect.com

Nickel complexes have recently been presented as prospective catalytic materials for hydrogen H2 evolution by hydrolysis of sodium borohydride NaBH4. An attractive complex is nickel HYDRAZINE NITRATE (cas 13464-97-6) [Ni(N2H4)3][NO3]2 for which little variations in the synthesis procedure result in different morphologies like hexagonal plates, clews and discs. In our conditions, the clews have the better catalytic activity owing to more defects and more active sites. There is an effect of the morphology on the catalytic activity. However, the H2 evolution curves (regardless the initial morphology) show an induction period during which the complex (purple violet in color) evolves into a catalytically active form (fine black powder). The evolution is featured by changes in morphology and chemical state of nickel. The catalytically active form is even more active than the pristine complex: it shows a higher H2 generation rate (three times higher in the best case). The starting complexes and the “reduced” counterparts have been then characterized (e.g. SEM, FTIR, XRD, XPS) to better understand the aforementioned evolutions. One of our main conclusions is that there are some marked analogies between our nickel-based catalysts and the much-investigated cobalt-based catalysts.

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