On the nature of tetravalent terbium in carbonate-hydroxide solutions
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Add time:08/08/2019 Source:sciencedirect.com
The oxidation of Tb(III) in K2CO3-KOH solution was studied. The concentrations of terbium, carbonate and hydroxide ions are critical for generation and stabilization of Tb(IV). Redox titrations of Tb(IV) with the Fe(CN)64− ion and the analysis of Tb(IV) precipitates indicate that the Tb(IV) complex in solution has a clustered nature.
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