Chiral 1-(1,3-dithian-2-yl) prop-2-en-1-ols: new scaffolds for enantiopure α-hydroxyaldehydes
-
Add time:08/05/2019 Source:sciencedirect.com
We have demonstrated that chiral 1-(1,3-dithian-2-yl)prop-2-en-1-ols as new scaffolds, obtained by enzyme-catalyzed kinetic resolution, undergo Suzuki-Miyaura cross-couplings and hydroformylation smoothly. Also, we have found that a 1,3-dithianyl group of the products can be removed without any erosion of the enantiopurity under mild conditions. A new access to a variety of enantiopure α-hydroxyaldehydes with ensured absolute configuration is described.
We also recommend Trading Suppliers and Manufacturers of 3-(1,3-DITHIAN-2-YL)-PENTANE-2,4-DIONE (cas 100596-16-5). Pls Click Website Link as below: cas 100596-16-5 suppliers
Prev:The synthesis of A 1-alkenyl thioether of glycerol
Next:Electronic control of product formation in the rearrangement of 1,3-dithian-2-yl-arylmethanols) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- An improved annelation method with methyl2-(1,3-dithian-2-yl)benzoate as a bidentate synthon08/10/2019
- Synthesis and reactivity of 2-(1,3-dithian-2-yl)indoles. IV. Influence of the N,N-diethylcarbamoyl indole protecting group08/09/2019
- Synthetic applications of 2-(1,3-Dithian-2-yl)indoles V.1 asymmetric synthesis of dasycarpidone-type indole alkaloids08/08/2019
- Synthetic applications of 2-(1,3-dithian-2-yl)indoles VI.1 Synthesis of 20-epidasycarpidone08/07/2019
- Electronic control of product formation in the rearrangement of 1,3-dithian-2-yl-arylmethanols08/06/2019
