A new precursor for organo-osmium complexes
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Add time:08/08/2019 Source:sciencedirect.com
The use of potassium osmate, K2[OsO2(OH)4], as a precursor for some cyclopentadienyl-osmium complexes is described. The X-ray structures of OsBr(PPh3)2Cp, OsCl(dppe)Cp and OsX(dppe)Cp∗ (X = Cl, Br) are reported.
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Next:Synthesis, characterization and crystal structures of osmium–rhodium mixed-metal clusters containing pentamethylcyclopentadienyl ligand: [Os3Rh(μ-CO)2(CO)9(η5-Cp*)], [Os3Rh2(μ-H)(μ-CO)2(CO)8(η5-Cp*)(μ2-η5,η1-CH2C5Me4)] and [Os3Rh(μ3-H)(μ-Cl)(μ-CO)(CO)9(η5-Cp*)]) - 【Back】【Close 】【Print】【Add to favorite 】
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