Triangular barium macrocyclic complex encapsulating perchlorate ions

Add time:08/05/2019    Source:sciencedirect.com

A novel unique tetraimine Schiff-base macrocyclic barium complex, derived by the template reaction of 4-chloro-2,6-diacetylpyridine with 1,2-diaminoethane, was formed. In the solid state this barium complex exhibits trinuclear motifs with a triangular ring of the macrocyclic ligands and encapsulated perchlorate anions. Additionally, each macrocycle is functionalised in the `head' framework, and so has the potential of further reactions.

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