Synthesis and structure of heteroleptic ytterbium (II) Tetrahydroborate (cas 16971-29-2) complexes

Add time:08/06/2019    Source:sciencedirect.com

The synthesis and characterization of (TptBu,Me)Yb(BH4)(THF)n (n = 0, 3; n = 1, 4) complexes are reported. The compounds represent rare examples of lanthanide (II) Tetrahydroborate (cas 16971-29-2) complexes. The X-ray crystal structure of complex 4 has been determined and it shows a monomeric, formally seven coordinate ytterbium center, bearing one κ3 bonded TptBu,Me ligand, a tetrahydroborate ligand and a coordinated THF molecule. The tetrahydroborate ligand binds in a κ3 fashion, via three bridging hydrogen atoms. IR spectroscopy data are consistent with the solid-state structure and the corresponding BD4 analog of 4 shows the expected IR isotope shifts. The 1H NMR spectra of 3 and 4 shows one set of resonances each for the BH4 and the pyrazolylborate ligands indicating dynamic solution behavior. For complex 3, although X-ray quality crystals could not be obtained, the IR and NMR data are consistent with its formulation as the solvent-free analog of complex 4 with κ3-bonded BH4 ligand.

We also recommend Trading Suppliers and Manufacturers of Tetrahydroborate (cas 16971-29-2). Pls Click Website Link as below: cas 16971-29-2 suppliers

Prev:Tetrahydroborate (cas 16971-29-2)s as new hydrogen storage materials
Next:π-Stacking motifs in the crystal structures of bis(phosphine) copper(I) η2-Tetrahydroborate (cas 16971-29-2) complexes)