Structure of a piperidine-modified calix[4]arene derivative and spectral resolution of its interaction with rare earth metals with chemometric methods

Add time:08/08/2019    Source:sciencedirect.com

A piperidine-modified calix[4]arene derivative was synthesized and its structure was confirmed with X-ray diffraction data. UV–visible spectroscopy was used to study its molecular recognition of rare earth ions. The results revealed the calix[4]arene derivative could separate tight metal picrate ion pairs by complexation with the rare earth metal ions in tetrahydrofuran. Resolution of the UV–visible spectra with chemometric methods revealed that the derivative and the rare earth ions Eu3+, Dy3+, and Tb3+ formed ML2 complexes with stability constants of 108.26, 108.29, and 107.41 respectively.

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