A simplified synthesis of Podophyllotoxin glucoside (cas 16481-54-2) derivatives
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Add time:08/07/2019 Source:sciencedirect.com
Podophyllotoxin glucoside (cas 16481-54-2) derivatives (Etoposide, Teniposide etc.) were synthesized from Podohyllotoxin by 5 steps of reactions. The method has many advantages, such as no need of protecting 4′-hydroxy, decrease of 2 reactions, and increase of more than 10% in total yield, in comparison with the conventional process. In this paper, alcoholysis reaction conditions were carefully studied and 5 metals as catalytic agent were selected. The new alcoholysis reaction is characterized by simple procedures, good quality and high yield.
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