DFT study the adsorption of ethyl xanthate on the S-site of Cu-activated sphalerite (1 1 0) surface in the presence of water molecule

Add time:08/07/2019    Source:sciencedirect.com

The research investigates whether the copper activation of sphalerite can result in the adsorption of xanthate on the S-site of sphalerite surface at the atomic level. The adsorption of ethyl xanthate (EX) molecule on the un-activated and Cu-activated sphalerite (1 1 0) surface in the presence of water molecule was conducted by using the density functional theory (DFT). The DFT results showed that there was little chemical interaction between EX and S atom of the un-activated sphalerite (1 1 0) surface. However, the copper activation of sphalerite changed the properties of S atom by inducing a strong covalent interaction between EX and the S atom. The EX molecule did not only adsorbed on the metal atom, but also adsorbed on the S-site.

We also recommend Trading Suppliers and Manufacturers of Ethyl (S)-9,10-difluoro-3-methyl-7-oxo-2,3-dihydro-7H-pyrido[1,2,3-de]-1,4-benzoxazine-6-carboxylate (cas 106939-34-8). Pls Click Website Link as below: cas 106939-34-8 suppliers

Prev:Metal complexation induces antibiotic activity in S-ethyl-l
Next:Pretreatment of bamboo shoot shell with surfactant OP-10 in the acidified media for enhancing the biosynthesis of ethyl (S)-4-chloro-3-hydroxybutanoate)