Reactions of bis(pentafluorophenyl)methylsilane with organolithium and grignard reagents

Add time:08/06/2019    Source:sciencedirect.com

Bis(pentafluorophenyl)methylsilane (I) reacts with primary alkyllithium and Grignard reagents to give high yields of the pentafluorophenylmetallic species. The influence of steric factors upon the course of the reactions with a series of RLi and RMgX compounds including PhMgBr, i-PrMgBr and t-BuLi are considered.

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