The reactions of α-phenyl- and α-ferrocenylcarbinols with DIIRON NONACARBONYL (cas 15321-51-4)

Add time:08/07/2019    Source:sciencedirect.com

Diiron nonacarbonyl oxidized a series of α-phenylcarbinols to their corresponding aldehydes and ketones. In addition, this reagent converted 4-methoxybenzyl alcohol to 4-methoxybenzyl ether, albeit in low yield. Under the same reaction conditions, oxidation was minor with a group of α-ferrocenylcarbinols as ether synthesis was the major reaction with those substrates which could not dehydrate; however, stereoselective olefin synthesis predominated when elimination was possible.

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