A facile chiral pool synthesis of 9-epi-decarestrictine-D, decarestrictine-D and O

Add time:08/07/2019    Source:sciencedirect.com

A facile chiral pool total synthesis of 9-epi-decarestrictine-D, decarestrictine-D and O has been achieved from l-(+)-diethyl tartrate. The strategy utilized is conventional and flexible. Wittig homologation and Grubbs ring closing metathesis are the key reactions employed for the synthesis of the title molecules.

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