Is hexaamminecobalt(III/II) electron self-exchange spin-forbidden? Analogy to photochemical processes
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Add time:08/07/2019 Source:sciencedirect.com
The hypothesis that the electron self-exchange reaction of hexaamminecobalt(III/II) is spin-allowed and adiabatic is presented and compared to previous treatments of the reaction which considered it spin-forbidden. The hypothesis is based on the concept that since the reactant and product have the same spin, it is unnecessary to invoke interaction with other spin states to ‘allow’ the reaction. To justify the hypothesis, an analogy is drawn between the cobalt self-exchange reaction and the photochemical processes of triplet-triplet annihilation and triplet-triplet exchange.
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