Solid-phase synthesis of a naturally occurring β-(1→5)-linked d-galactofuranosyl heptamer containing the artificial linkage arm L-homoserine

Add time:08/09/2019    Source:sciencedirect.com

The glycosyl donor 2,3-di-O-benzoyl-5-O-levulinoyl-6-O-pivaloyl-β-D-Galactofuranosyl chloride and properly-protected L-homoserine covalently bound to polystyrene were employed for the stereoregular formation of a D-galactofuranosyl heptamer containing β-(1→)-interglycosidic bonds and a β-linked L-homoserine via a solid-phase approach

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