ESR study of vanadyl ion in triammonium citrate
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Add time:08/14/2019 Source:sciencedirect.com
ESR spectra of VO2+ doped triammonium citrate are recorded at room temperature. The observed spectra are fitted to a spin Hamiltonian of orthorhombic symmetry with gx = 2.003 ± 0.001, gy = 1.992 ± 0.001, gz = 1.940 ± 0.001, Ax = (56.0 ± 1) × 10−4cm−1, Ay = (63.9 ± 1) × 10−4cm−1 and Az = (166.5 ± 1) × 10−4cm−1. The covalency and Fermi contact terms are evaluated. The density of the crystal is evaluated to be 1.536 gm cm−3 and Z = 4 molecules/unit cell.
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