Synthesis of d- and l-myo-inositol 1-phosphorothioate, substrates for inositol monophosphatase

Add time:08/08/2019    Source:sciencedirect.com

The D- and L- enantiomers of myo-inositol 1-phosphorothioate have been synthesized from 2,3,4,5,6-pentakis-O-benzyl myo-inositol in 6 steps, both compounds are substrates for inositol monophosphatase. D-glucopyranose 6-phosphorothioate did not serve as a substrate for the enzyme inositol synthase in an alternative synthesis of L-myo-inositol 1-phosphorothioate.

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