A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12

Add time:08/08/2019    Source:sciencedirect.com

An isomer of C84 fullerene, D3d-C84(24)(CF3)12, has been isolated by the HPLC method from the products of trifluoromethylation of C84 fullerene mixture. Its molecular structure has been determined by a single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 12 CF3 groups are arranged as a loop of edge-sharing para-C6(CF3)2 hexagons. Isomer D6h-C84(24) has been identified in the form of a derivative for the first time.

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