Synthesis of (2-aminoethyl)ferrocenes from the reaction of lithium amides with Vinylferrocene (cas 1271-51-8)

Add time:08/15/2019    Source:sciencedirect.com

Lithium amides react with vinylferrocene in the presence of TMEDA to provide the corresponding (2-aminoethyl)ferrocenes in good to excellent yields. A range of secondary amines can be employed in this amidolithiation reaction, with cyclic derivatives affording particularly good yields of the 2-aminoethyl-substituted ferrocene product. This operationally simple procedure provides one of the most straightforward routes to this class of mono-substituted ferrocene.

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