Formation of 1,2-oligomeric ferrocenes from ullmann reactions of Iodoferrocene (cas 1273-76-3)s

Add time:08/12/2019    Source:sciencedirect.com

A mixed Ullman reaction between iodoferrocene and 1,2-diiodoferrocene as well as an Ullmann reaction involving only 1,2-diiodoferrocene both produce biferrocene as well as linear 1,2-oligomeric ferrocenes, including 1,2-terferrocene, meso-1,2-quaterferrocene, dl-1,2-quaterferrocene and several isomeric 1,2-quinqueferrocenes. The formation, spectral characteristics and structures of these products are discussed.

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