Metallic macrocycles built-up from ferrocenedicarboxylate and ancillary nitrogen heterocycles: Hydrothermal synthesis, crystal structures and electrochemical properties

Add time:08/09/2019    Source:sciencedirect.com

Four novel metal–organic macrocyclic compounds, Co2(OH2)2(2,2′-bipy)2(O2CFcCO2)2·2H2O (1), Co2(OH2)2(1,10′-phen)2(O2CFcCO2)2·2H2O (2), Co2(OH2)2(5,5′-dimethyl-2,2′-bipy)2(O2CFcCO2)2 (3) and Cu6(2,2′-bipy)6(O2CFcCO2)6·3H2O (4), have been obtained by hydrothermal synthesis and structurally characterized by single crystal diffraction. Their electrochemical properties were evaluated by solution-state differential pulse voltammetry. The voltammograms of all four compounds show two peaks which are separated by large potential values indicating a strong interaction between two ferrocene moieties in each structure.

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