Some synthetic applications of the reactivity of methyl 2-fluoro-3-(phenylthio)acrylate

Add time:08/11/2019    Source:sciencedirect.com

The synthetic usefulness of the title compound is demonstrated through its reactivity towards thio and amino nucleophiles as well as tin-centred radicals. The synthesis of a 2-fluoro analogue of a natural fungicide (Sinharine) is reported. We also show that 3-aryl-2-fluoropropenoates could be obtained via Stille coupling between an aryl iodide and a 3-tributylstannyl-2-fluoropropenoate.

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