Infrared spectroscopy and molecular properties of Chlorosyl (cas 12301-79-0) fluoride, FClO

Add time:08/09/2019    Source:sciencedirect.com

The structure of the very reactive, yet fairly long-lived, FClO molecule has been determined experimentally for the first time. Analysis of the high-resolution infrared spectrum of its ν1 band provided the spectroscopic constants needed. FClO was obtained as the main product of the reaction between ClF3 and H2O under slow-flow conditions. A preliminary analysis of the ν2 band and a comparison of the FClO structural properties with those of related molecules are also presented.

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