On the photosynthesis of dioxygen(1+) hexafluoroarsenate in the systems O2-F2-AsF5, OF2-AsF5 and O2-OF2-AsF5

Add time:08/09/2019    Source:sciencedirect.com

The photochemical reactions in the systems O2-F2-AsF5, OF2-AsF5 and O2-OF2-AsF5, yielding O2AsF6 as the reaction product were investigated. The influence of the mole ratio of the reactants upon the rate of formation of O2AsF6 was studied and a reaction mechanism is suggested which is based on the formation of O2F· radicals. Regarding the preparation of O2AsF6, the best results were obtained using the system O2-F2-AsF5 with the mole ratio 1:1-1.5:1.

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