Synthesis of (2R, 3S)-methyl-2-fluoro-3-(n-benzoylamino)-3-phenylpropanoate: Modified side chain of taxol

Add time:08/11/2019    Source:sciencedirect.com

Methyl-2-fluoro-3-(N-benzoylamino)-3-phenylpropanoate 2 and 3, fluorine analogs of the C-13 side chain of taxol, were synthesized by electrophilic fluorination of the dianion of methyl (R)-(−)-(N-benzoyl)-3-amino-3-phenylpropanoale (4).

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