The behavior of alkoxides with allyl(chloromethyl)dimethylsilanes and (chloromethyl)dimethylvinylsilane; the abilities of allyl and vinyl groups to migrate from pentacoordinate silicon
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Add time:07/14/2019 Source:sciencedirect.com
Sodium methoxide in tetrahydrofuran attacks silicon in allyl(chloromethyl)dimethylsilane and in (chloromethyl)dimethylvinylsilane with displacement of chloride and 1,2-migration of the allyl and the vinyl groups to give 1-(3-butenyl)methoxydimethylsilane and allylmethoxydimethylsilane.
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