Synthesis, structural characterization and DFT calculation on a square-planar Ni(II) complex of a compartmental Schiff base ligand

Add time:08/09/2019    Source:sciencedirect.com

Reaction of a symmetric compartmental Schiff-base ligand, (H2L) with nickel(II) perchlorate hexahydrate in 1:1 M ratio in methanol gives rise to a mononuclear nickel(II) compound, NiL (1). The compound has been characterized by C, H, N microanalyses and UV–Vis spectra. The single crystal X-ray diffraction studies reveal a square planar geometry around the Ni(II) center. The compound crystallizes in monoclinic system with space group C2/c with a = 21.6425(6), b = 9.9481(3), c = 13.1958(4) Å, β = 107.728(2)°, V = 2706.16(14) Å3 and Z = 4. Ground state DFT optimization and TDDFT calculations on the ligand and complex were performed to get their UV–Vis spectral pattern.

We also recommend Trading Suppliers and Manufacturers of NICKEL(II) PERCHLORATE HEXAHYDRATE (cas 13520-61-1). Pls Click Website Link as below: cas 13520-61-1 suppliers

Prev:Ferrous sulfate based low temperature synthesis and magnetic properties of nickel ferrite nanostructures
Next:Synthesis, molecular structure and DFT studies of two heteroleptic nickel(II) s-triazine pincer type complexes)