An efficient chemoenzymic access to optically active myo-inositol polyphosphates
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Add time:08/11/2019 Source:sciencedirect.com
The 1,4,5-tris-, 1,3,4-tris-, and 1,3,4,5-tetrakis-phosphates of 1d-myo-inositol have been prepared in their enantiomerically pure forms from the two enantiomers of 1,2:5,6-di-O-cyclohexylidene-myo-inositol. A facile enzymic preparation is also described of these chiral intermediates through enantiospecific deacylation of the corresponding racemic esters.
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