Infrared spectra of ordered crystalline ethane and ETHANE-D6 (cas 1632-99-1)

Add time:07/12/2019    Source:sciencedirect.com

Spectra are reported for crystalline ethane, ethane-d2 and their mutual solid solutions. The evidence indicates definitely at least two molecules per unit cell and that there cannot be a three-fold symmetry axis through the molecules. A structure for the solid is tentatively proposed; it is based on a structure distorted from hexagonal.The shifts of vibrations from gas to solid are remarkably small in most cases; unusually large shifts in the C2D6 molecule are believed due to some improper choices of band centers in the gas spectra.

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