Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes
-
Add time:08/15/2019 Source:sciencedirect.com
Two pincer-type nickel iminophosphinite complexes, [(2-(CHNR)-6-(OPR′2)C6H3)NiCl] (R = 2,6-iPr2C6H3, R′ = Ph (2a) or iPr (2b)), were synthesized from the reactions of bis(1,5-cyclooctadiene)nickel(0) and corresponding iminophosphinite ligands. The solid state structures of the nickel pincer complexes were determined by X-ray single crystal diffraction studies. They were successfully employed in the Kumada reaction of non-activated aryl chlorides and phenylmagnesium bromide at room temperature.
► We prepared novel nickel complexes bearing pincer-type iminophopshinite ligands. ► The complexes are air-stable and thermally robust. ► They have been successfully employed in the Kumada reaction of aryl chlorides.
We also recommend Trading Suppliers and Manufacturers of BIS(1,5-CYCLOOCTADIENE)NICKEL(0) (cas 1295-35-8). Pls Click Website Link as below: cas 1295-35-8 suppliers
Prev:Ames test evaluation of two commercially available zero-valent nickel compounds
Next:Reactions of bis(η4-1,5-cyclooctadiene)nickel(0) with transition metal halides, and the crystal structure of μ-dichloro-bis(tetrahydrofuran)hexacarbonyldimanganese) - 【Back】【Close 】【Print】【Add to favorite 】
- Related Information
- Oxidative assembly of octahedral nickel(II)-tris(3,5-dimethylpyrazol-1-yl)methane (Tpm∗) complexes by reaction of Ni(COD)2 (COD = 1,5-cyclooctadiene) with putative oxene and nitrene precursors08/17/2019
- Reactions of bis(η4-1,5-cyclooctadiene)nickel(0) with transition metal halides, and the crystal structure of μ-dichloro-bis(tetrahydrofuran)hexacarbonyldimanganese08/16/2019
- Ames test evaluation of two commercially available zero-valent nickel compounds08/14/2019
- Cycloisomerization and [2 + 2]cyclodimerization of 1,5-cyclooctadiene catalyzed with the Ni(COD)2/BF3·OEt2 system08/13/2019
- Ethylene homopolymerization by novel Ziegler Natta-type catalytic systems obtained by oxidative addition of salicylaldimine ligands to bis(1,5-cyclooctadiene)nickel(0) and methylalumoxane08/12/2019
- Thermodynamic study of volatile iridium (I) complexes with 1,5-cyclooctadiene and acetylacetonato derivatives: Effect of (O,O) and (O,N) coordination sites08/11/2019
- Cationic indenylnickel complexes bearing a 1,5-cyclooctadiene ligand: Synthesis and characterization08/10/2019