First detection of the silylgermylene (H3SiGeH) and D4-silylgermylene (D3SiGeD) molecules in low temperature silane–germane ices

Add time:08/10/2019    Source:sciencedirect.com

The thermodynamically most stable GeSiH4 isomer – silylgermylene (H3SiGeH(X1A′)) – and its perdeuterated counterpart were detected for the first time via infrared spectroscopy in low temperature silane (SiH4) – germane (GeH4) and D4-silane – D4-germane ices upon irradiation with energetic electrons through the ν5 and ν3 fundamentals at 860 cm−1 and at 1309 cm−1, respectively. Our kinetic studies suggest that silylgermylene is formed via decomposition of chemically activated silylgermane (H3SiGeH3) precursors.

We also recommend Trading Suppliers and Manufacturers of SILANE-D4 (cas 13537-07-0). Pls Click Website Link as below: cas 13537-07-0 suppliers

Prev:Deuterium and DEUTERIUM SULFIDE (cas 13536-94-2) adsorption on MoS2(0001)
Next:Study of phase stability and isotope effect in dysprosium trihydride (cas 13537-09-2) at high pressure)