The dissociative electroionization of ammonia and AMMONIA-D3 (cas 13550-49-7). III. The N+ dissociation channel. general conclusions about the dissociation of NH3+
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Add time:08/19/2019 Source:sciencedirect.com
The dissociative ionization of NH3 is investigated in its N+ dissociation channel in the 20–50 eV electron energy range. Both the translational energy distribution and the appearance energies are measured. The kinetic energy versus appearance energy plot reveals seven N+ producing processes. Near the onset (22.5–24.0 eV) dissociative autoionization occurs whereas direct dissociative ionization produces N+ in the 24.5–30 eV range. Above 35 eV mainly N+/H+ ion pairs are formed at the expense of doubly ionized states. The dissociative electroionization work on NH3 being completed, a review of the results is presented.
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